Preheat the oven to 350°F (175°C). Do not use the convection (fan) setting.
Grease a large, rectangular baking dish and set aside.
Whisk the dry ingredients together (cake flour, cocoa powder, sugar, baking powder, baking soda, and salt) and set aside.
In the bowl of a stand mixer, add the buttermilk, espresso powder, vegetable oil, and sour cream. Mix to combine, add the eggs, and mix again. Reduce the mixer speed to low, and slowly add in the hot water. Increase the speed to medium, gradually add the dry ingredients, and mix until smooth.
Add the batter to the greased baking dish, and bake for 30-35 minutes, or until a toothpick inserted into the center comes out clean. Allow to cool in pans for up to 45 minutes, then cool fully on a cooling rack.
While the cake is cooling, prepare the cherry filling and stabilized whipped cream.